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The p-conjugated semiconductor structures (polymers) present a growing
interest in particular in the field of communication and information technologies.
Organic Field-effect Transistors (OFET), light-emitting diodes, and solar
batteries are possible applications for these organic semiconductors.
One of the key points to reach high performances with such devices using
conjugated polymers is the elaboration of highly organized structures
on surfaces on the single-molecular scale. Most of the studies about surface
polymerization have been performed on conducting substrates. Playing with
the organic films composition, the strength of the interaction with the
substrate and the exposition of thin films to additional chemical species
will give the opportunity to tune the physical properties of organic materials
for applications in nanoelectronics. The specific goal of my proposed
research is to study the mechanism of molecular (polymer) adsorption on
metallic substrates and determine the structural and electronic properties
of molecular self-organized. The development of this project will require
the use of surfaces science techniques (MBE growth, STM, LEED/Auger and
photoemission spectroscopy).
List of publications:
L.A. Cardenas, Y. Fagot-Revurat, L. Moreau, B. Kierren
and D. Malterre, “Surface-state bipolaron formation on a triangular
lattice in the sp-type alkali/Si(111) Mott insulator”, Phys. Rev.
Lett. 103, 046804 (2009).
L.A. Cardenas, Y. Fagot-Revurat L. Moreau, B. Kierren,
and D. Malterre, “Novel bi-polaronic ground state in K/Si(111):B”;
e-J. Surf. Sci. Nanotech. Vol. 7 (2009) 259-263.
C. Tournier-Colletta, L.A. Cardenas, Y. Fagot-Revurat,
B. Kierren, D. Malterre, “Spectral function of the K/Si(111) : B
surface state: the bipolaronic CDW scenario”. To be published in
J. Elec. Spec.
L.A. Cardenass, Y. Fagot-Revurat, B. Kierren, D. Malterre,
C. Didiot, P. Aebi. “Determination of the adsorption sites of alkali
on the Si(111)(?3x?3)R30° : B surface structure by dynamical LEED”.
To be published in Surf. Sci.
L.A. Cardenas, A. Rodriguez, F. Rueda, R. Casanova, A.
Loaiza, “Oxygen and Hydrogen Adsorption studies by means of the
Kelvin probe”; Latin American review of metallurgy and materials.
24 (2006).
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